Head to Head
| Netherlands Eredivisie Women | 2024/12/07 15:30 | Ajax (W) v PSV (W) | W | 0-2 |
| Netherlands Cup Women | 2024/05/15 17:30 | Ajax (W) v PSV (W) | D | 1-1 |
| Netherlands Eredivisie Women | 2024/05/01 16:45 | Ajax (W) v PSV (W) | L | 2-1 |
| Netherlands Eredivisie Women | 2023/12/09 13:00 | PSV (W) v Ajax (W) | D | 3-3 |
| Netherlands Cup Women | 2023/05/22 17:00 | PSV (W) v Ajax (W) | L | 1-3 |
| Netherlands Cup Women | 2023/05/14 12:30 | Ajax (W) v PSV (W) | L | 5-2 |
| Netherlands Eredivisie Women | 2023/02/05 11:15 | PSV (W) v Ajax (W) | L | 1-2 |
| Netherlands Eredivisie Women | 2022/11/20 11:15 | Ajax (W) v PSV (W) | L | 1-0 |
| Netherlands Cup Women | 2022/05/29 12:30 | Ajax (W) v PSV (W) | L | 3-0 |
| Netherlands Cup Women | 2022/05/26 12:30 | PSV (W) v Ajax (W) | L | 0-2 |
| Netherlands Cup Women | 2022/04/18 12:30 | Ajax (W) v PSV (W) | L | 2-1 |
| Netherlands Eredivisie Women | 2022/03/27 10:15 | Ajax (W) v PSV (W) | D | 0-0 |
| Netherlands Eredivisie Women | 2022/02/28 18:30 | PSV (W) v Ajax (W) | L | 1-2 |
| Netherlands Eredivisie Women | 2021/11/07 11:15 | Ajax (W) v PSV (W) | L | 5-1 |
| Netherlands Eredivisie Women | 2021/05/23 12:30 | Ajax (W) v PSV (W) | L | 3-2 |
| Netherlands Eredivisie Women | 2021/04/25 10:15 | PSV (W) v Ajax (W) | W | 3-1 |
| Netherlands Cup Women | 2021/04/18 10:15 | PSV (W) v Ajax (W) | W | 1-0 |
| Netherlands Eredivisie Women | 2021/03/17 19:00 | PSV (W) v Ajax (W) | W | 2-1 |
| Netherlands Cup Women | 2020/12/04 18:30 | PSV (W) v Ajax (W) | D | 2-2 |
| Netherlands Eredivisie Women | 2020/10/04 10:15 | Ajax (W) v PSV (W) | L | 2-0 |
| Netherlands Eredivisie Women | 2019/10/13 12:30 | Ajax (W) v PSV (W) | W | 1-4 |
| Netherlands Eredivisie Women | 2019/04/19 17:30 | PSV (W) v Ajax (W) | L | 0-1 |
| Netherlands Eredivisie Women | 2019/02/22 18:30 | Ajax (W) v PSV (W) | L | 1-0 |
| Netherlands Eredivisie Women | 2019/02/08 18:30 | Ajax (W) v PSV (W) | L | 2-0 |
| Netherlands Eredivisie Women | 2018/11/16 18:30 | PSV (W) v Ajax (W) | W | 1-0 |
| Netherlands Cup Women | 2018/06/02 16:30 | Ajax (W) v PSV (W) | L | 3-1 |
| Netherlands Eredivisie Women | 2018/05/27 12:30 | Ajax (W) v PSV (W) | D | 2-2 |
| Netherlands Eredivisie Women | 2018/04/24 17:30 | PSV (W) v Ajax (W) | L | 2-6 |
| Netherlands Eredivisie Women | 2018/02/23 18:30 | Ajax (W) v PSV (W) | W | 0-3 |
| Netherlands Eredivisie Women | 2017/11/19 13:30 | PSV (W) v Ajax (W) | L | 1-2 |
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